Over 1,500 players and spectators will converge on Port Macquarie for the four day event which showcases the top under 18’s talent in Australia. The championships have returned to the traditional Under 18’s format after the inclusion of the Under 20’s division in 2008, with 36 teams competing at the tournament.The event is Port Macquarie’s second national Touch Football tournament this year, after the National Touch League was hosted at the stadium in March.QSST’s Boys and Girls teams will both be looking to again take a clean sweep of the Under 18’s titles after their dominance at the 2008 championships, but will face tough competition from NSWCHS, NSWCCC, SQBD Sharks and Brisbane City Cobras in both divisions. Local hopes will be high after the Northern Eagles fifth placing in the Under 18’s Girls last year, and the experience of their coach – Australian Women’s 20’s player, Stephanie Halpin, will be of great benefit to the team. The Under 18’s Boys team will be looking to improve on their result of 14th at the 2008 championships with the help of the talent Port Macquarie brothers, Nick and Matt Bale. The round games will be played from Wednesday to Friday, before the semi finals and finals are played on Saturday. To keep updated on scores and news throughout the tournament, please visit the National Youth Championships website: http://www.nyc.mytouchfooty.com
Update: Webb has deleted the post from her Instagram page. Perhaps she jumped the gun on the news.Earlier: Katherine Webb will be returning to your television screens, college football fans – even if just for a brief moment. Friday, Webb, on Instagram, announced that on behalf of Pizza Hut, she’ll be making a “special appearance” at College GameDay tomorrow. She’ll apparently be holding a sign – and fans can win free pizza if they enter the code on it.Webb, now a model, was the talk of the 2013 BCS National Championship Game after announcers Brent Musburger and Kirk Herbstreit commented on her looks during the broadcast. She was then the girlfriend of Crimson Tide QB AJ McCarron – they’re now married.Will it actually be Webb in the flesh tomorrow? We’ll find out.
zoom Norwegian tanker shipping giant Frontline has shelved its plans to purchase its US-based rival Gener8 Maritime, the Wall Street Journal reported.Fredriksen said earlier that he was looking into the purchase of a ship operator that ran at least 20 VLCCs, with Gener8 Maritime being singled out as the likely candidate.A vessel combination deal between Frontline and Gener8 Maritime, which operates a fleet of 23 tankers, would have created the world’s biggest tanker fleet, featuring 43 very large crude carriers.Frontline was linked with Gener8 Maritime after the Norwegian firm abandoned plans to acquire DHT Holdings after a number of unsuccessful bids for outstanding shares of common stock in the compatriot tanker owner.However, DHT’s Board turned down several offers from Frontline, deeming them inadequate.Following the latest dismissal of legal action against DHT Holdings by the Marshall Islands court, Frontline seems to have admitted defeat and is moving on.“We will not spend time pursuing the DHT track,” Reuters reported earlier today citing Frontline’s Chief Executive Robert Hvide Macleod as saying.Furthermore, prompted by the current market conditions in the sector, Fredriksen’s firm reportedly decided to abstain from merger and acquisition moves for the time being.World Maritime News Staff
Brighton & Hove Albion striker Florin Andone was buzzing after scoring his third goal for the club in their 3-1 win at Bournemouth on Saturday.Andone scored Brighton’s third goal in their 3-1 victory at the Vitality Stadium on Saturday as the Seagulls advanced to the fourth round of the Emirates FA Cup.“It’s my style and I live for those moments, I’m very happy because it will give me confidence as a striker to score,” he told the club’s website.“I feel a real connection with the fans, I think they love me, that’s the feeling I get, and I want to thank them for all their support and encouragement to the team.“The win is good for us and it was important for a lot of the squad to get good game time this afternoon.Pep Guardiola: “Aymeric Laporte’s injury doesn’t look good” Andrew Smyth – August 31, 2019 Manchester City boss Pep Guardiola admits Aymeric Laporte’s injury “does not look good” and fears the defender will be out for a long time.“We played very well and deserved the victory, the feeling when I scored was crazy – sometimes you lose yourself in the moment after getting a goal and that’s what happened.“We’re in good form in the league and won today, this is the way to continue.“For me personally, I work hard every day in training in a very competitive squad – both I and Glenn [Murray] push one another and get on really well.“Our relationship is great – he’s a really good guy, this is the way we must continue – the group is very close and strong. It doesn’t matter who is playing and who isn’t, because the team is very competitive.”
Facebook0TwitterEmailPrintFriendly分享Kenai Peninsula Stream Watch volunteers will be kicking off the first day of the beach clean-up and fitness series ‘trash-ercise’, on Tuesday, July 10. Stream Watch Started in 1994 by a group of concerned citizens and the Chugach National Forest, this volunteer driven program has grown from a grassroots collective of 10 to a volunteer movement of 180+ volunteers who are making a difference for rivers on Alaska’s Kenai Peninsula. Volunteers receive all of the training and supplies, including volunteer campsites, to share information on river protection while completing hands-on projects on the Kasilof, Kenai and Russian Rivers. According to Stream Watch it’s “a *shore* way to keep our community clean and hearts healthy.” Stream Watch will provide trash bags to volunteers. The ‘trash-ercise’ series will take place on every Tuesday through July and August. The series is open to runners, walkers, or fat bikers who volunteer their time to pick up beach litter. Volunteers will meet each week at the North Kasilof Beach. From Soldotna, head south on Sterling Highway for 13.5 miles. Take a right onto K-Beach Road, and in 4.8 miles turn left onto Kasilof Beach Stub. For any questions, please call (907) 260-5449 x 1205. Photo courtesy of Stream Watch
Journal information: Science (Phys.org)—A team of researchers at Princeton University and a Bristol-Myers Squibb associate have developed a means for creating reactive ammonium radical cations using flashes of blue light. In their paper published in the journal Science, the team describes their new technique and the ways they believe it could be used to create substituted amines. Travis Buchanan and Kami Hull with the University of Illinois offer a Perspectives piece on the work done by the team and the expected impact the new technique is likely to have on organic chemistry. As Buchanan and Hull note, amines (which are molecules that have a C—N bond) are very important in the pharmaceutical industry—approximately 84 percent of pharmaceuticals contain amines. But, as they also note, conventional processes that are used to create carbon-nitrogen bonds involve what they describe as energetically unfavorable reactions—they are inefficient. The process typically involves hydroamination which is where a N—H bond is directly added to a C—C molecule, or even to a triple. In this new effort, the researchers report on a new method using a simple blue light from an LED that gets the job done in a more efficient way.The team at Princeton used a photochemical approach that allowed for the creation of reactive ammonium radical cations using a flashing blue light (for 12 hours), which in turn was used to form the desired isomers. They used the blue light to excite an iridium complex to oxidize the amine, allowing for efficient bonding with the olefin. A thiophenol cocatalyst was then used to move the electron back. The researchers report that their technique could be uses for a variety of olefin and amine compounds allowing for using amines in pharmaceuticals in new and useful ways—some of which, they report, could not be created any other way. Furthermore, they note, the technique is completely atom economical—all of the atoms in the starting materials wound up in the end product.Buchanan and Hull suggest the new approach could represent a transformative approach to amine synthesis, noting that the researchers used their technique to animate a sample of every existing olefin type. A new method cuts the cost of drug-building chemicals Explore further This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only. More information: Andrew J. Musacchio et al. Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines, Science (2017). DOI: 10.1126/science.aal3010AbstractThe intermolecular hydroamination of unactivated alkenes with simple dialkyl amines remains an unsolved problem in organic synthesis. We report a catalytic protocol for efficient additions of cyclic and acyclic secondary alkyl amines to a wide range of alkyl olefins with complete anti-Markovnikov regioselectivity. In this process, carbon-nitrogen bond formation proceeds through a key aminium radical cation intermediate that is generated via electron transfer between an excited-state iridium photocatalyst and an amine substrate. These reactions are redox-neutral and completely atom-economical, exhibit broad functional group tolerance, and occur readily at room temperature under visible light irradiation. Certain tertiary amine products generated through this method are formally endergonic relative to their constituent olefin and amine starting materials and thus are not accessible via direct coupling with conventional ground-state catalysts. © 2017 Phys.org Citation: Blue light allows for making carbon-nitrogen bonds without ‘energetically unfavorable’ reactions (2017, February 17) retrieved 18 August 2019 from https://phys.org/news/2017-02-blue-carbon-nitrogen-bonds-energetically-unfavorable.html Proposed catalytic cycle for hydroamination. Credit: (c) Science (2017). DOI: 10.1126/science.aal3010
Kolkata: The Central Bureau of Investigation (CBI) questioned the former CEO of Narada News Mathew Samuel once again on Friday, sources said. Samuel went to the office of CBI in Kolkata in connection with the Narada sting operation case. Sources said that the CBI officers have questioned Mathew in connection with the original video footages of the sting operation. It has been learnt that the investigating officers have not got a satisfactory answer in this connection.Sources said that the matter related to the Muchipara case in which a former Central minister from Bihar had received a call demanding extortion money of Rs 5 crore and was threatened with some video footages. Storage devices containing video footages were recovered from a hotel room at Muchipara.
Netflix is searching for a new marketing boss after veteran chief marketing officer Leslie Kilgore was moved to non-executive director of the Netflix board.Jessie Becker, who was previously vice-president, marketing, will become chief marketing officer on an interim basis, while the company conducts an external search. Kilgore has been with Netflix for the last 12 years after previously having worked at Amazon and Proctor & Gamble.Separately, Netflix has promoted Jonathan Friedland as chief communications officer. Both Becker and Friedland report to Netflix chief executive Reed Hastings.
A Johannesburg-based online TV service has acquired UK and US streaming rights to the Nollywood movie adaptation of best-selling novel Half of a Yellow Sun.PanaTV bills itself a “pioneer” in Africa, and said the acquisition of Half of a Yellow Sun “falls in line with our mission to tell the African story to the world, by making Africa’s stories easily accessible through the internet”.The UK deal was made with London-based distributor Soda Pictures, and the US agreement with Monterey Media.Half of a Yellow Sun stars Thandie Newton and Anika Noni Rose as a pair of sister caught up in the Nigerian Civil War. It also stars Academy Award-nominee Chiwetel Ejiofor.It launched in the US on June 29, where it has a limited exclusive window before becoming non-exclusive, and will go out in the UK from August.The service aims to legally stream African-produced content to online audiences worldwide. It has around 8,000 hours of shows comprising movies, music, television, lifestyle, educational and kids content.